Thread lock

ABSTRACT

The method of making a friction locking fastener of the type having in the thread grooves a first deposit formed of a mixture of an uncured epoxy resin and a radiation-curable, film-forming material, and a second deposit of a fluid curing agent and a radiation-curable, film-forming material. The deposits are made in the thread grooves at circumferentially spaced locations so that a very thin coating of the radiation-curable, film-forming material develops at the surface of each deposit. The deposits are subjected to high intensity ultraviolet radiation for a few seconds to transform the coatings developed on the surfaces of the deposits into thin, continuous, flexible, non-tacky protective films which cover the still fluid deposits in the thread grooves of the article. Alternatively, when one or both the resin and the curing agent are microencapsulated. They may be contained in a single mixture which includes the radiation-curable material. That mixture, when deposited and exposed to radiation, will form a protective film at the surface. The resin will not be polymerized until the capsule are ruptured.

This invention relates generally to a threaded member having a threadlocking material applied to the threads to oppose separation whenengaged with another threaded member, and refers more particularly to amethod of providing a protective coating over the thread lockingmaterial prior to engagement.

BACKGROUND AND SUMMARY OF THE INVENTION

Self-locking threaded fasteners have in the past been made by means of atwo-part adhesive, such as an uncured epoxy resin and a polymerizingagent. Deposits of the uncured resin and curing agent are applied to thethreads of the fastener. The deposits become mixed when the fastener isengaged with a mating member, effecting a cure of the resin to provide,a thread lock. The resin has also been micro-encapsulated and themicrocapsules mixed with the polymerizing agent to provide a slurrywhich is applied to the threads. U.S. Pat. No. 3,746,068 discussesmicro-encapsulation.

Protection films over the deposits protect them until the time when thefastener is actually engaged with a mating threaded member. Each depositmay be coated with polyvinyl alcohol in a water solution to form theprotective film. My prior U.S. Pat. Nos. 4,059,136 and 4,081,012 are ofinterest in this regard. My prior U.S. Pat. No. 4,325,985 discloses animprovement in which the deposits are coated with ultraviolet curable,protective films. Other patents of interest are U.S. Pat. Nos.3,489,599, 3,746,068 and 3,814,156.

The present invention is a further improvement in which ultravioletcurable material, rather than being applied as a subsequent coating, ismixed with the resin and curing agent prior to the deposit thereof onthe threads of the fastener. That portion of the ultraviolet curablematerial which is near the surface of the deposits is then cured byultraviolet light to form a protective skin or film.

These and other objects of the invention will become more apparent asthe following description proceeds, especially when considered with theaccompanying drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a side elevational view of a twin belt conveyor which is partof apparatus that may be used in the practice of the method of thisinvention.

FIG. 2 is a sectional view on the line 2--2 in FIG. 1.

FIG. 3 is a diagrammatic plan view of apparatus that may be used in thepractice of the method, including the conveyor shown in FIG. 1. Theapparatus illustrated is only one example of apparatus that may be usedin the practice of the invention.

FIG. 4 is an enlarged fragmentary view of a portion of a bolt showingthe deposited material and the protective films thereover.

DETAILED DESCRIPTION

Reference is made to the drawing as illustrative of a procedure inaccordance with the invention, where the uncured resin and the curingagent remain fluid and are protected by protective films until used.

A series of threaded fasteners or bolts 10 are supplied to the conveyor5. Conveyor 5 comprises a pair of horizontal, laterally spaced, parallelbelts 12 between which the bolts are suspended by their heads. Theconveyor belts are moved by means (not shown) in the direction of thearrow. The individual bolts are supplied to the conveyor at a loadingstation A. At this loading station, the bolts are at ambienttemperature, which may be assumed to be about 70° F. In practice, thebolts may be supported with their heads in contact with another,although they are shown spaced apart.

Preferably, the temperature of the bolts is raised between stations Aand B to about 90° F. This may be accomplished by heaters indicated at18.

At station B, applicators 14 and 16 on opposite sides of the beltconveyor deposit controlled amounts of fluid material onto oppositesides of the threaded portions of the bolts, The fluid deposits 15applied to one side of the bolts by the applicator 14 is a mixture ofuncured resin, in this instance epoxy resin, and a film-formingultraviolet curable material. The fluid deposits 17 applied to theopposite sides of the bolts by the applicator 16 is a mixture of acuring agent or hardener for the resin, in this instance tertiary amine,and the same film-forming ultraviolet curable material.

Applicators 14 and 16 may be of any suitable known type, and may, forexample, be of the type disclosed in the prior above identified patents.The fluid deposits have a viscosity such that they flow down into thethread grooves and laterally along the thread grooves, remainingessentially at the axially located zones of deposition, which may extendfor several threads along the bolt. That portion of the ultravioletcurable material in each deposit which is near or at the surface of thedeposit forms a very thin continuous coating.

Heat is again applied after the bolts move beyond applicators 14 and 16,by heaters 19.

The preheat of the bolts by heaters 18 and the post heat by heaters 19warms the bolts and the deposits and assists in the desired flow of thedeposits into the thread grooves. This "lay down" of the deposits alsoimproves the appearance of the coated bolt. Heaters 18 and 19 areoptional and are used only when necessary to achieve the desired flowand "lay down". When the method is carried out in a warm environment, asin summer time. both preheat and post heat may not be needed and can beomitted.

The fasteners continue their movement on the conveyor past station Cwhere there are ultraviolet cabinets 22 and 24 on opposite sides of theconveyor. The rate of advance of the bolts is such that the deposits onopposite sides of the bolts are exposed to high intensity radiation atstation C for only a very few seconds as, for example, less than 10seconds, and preferably between 2 and 5 seconds

The source of radiation may be elongated ultraviolet radiating tubes,backed by reflectors, and positioned on both sides of the conveyorbeneath the conveyor belts and rated at 200 watts per inch.

The effect of the ultraviolet radiation at station C is to convert theultraviolet curable material at the surface of the deposits 15 and 17 toa fully cured and set film or skin 26.

The films or skins formed over the deposits 15 and 17 by this processare extremely thin, flexible, dry, non-tacky and continuous, lacking anypin holes associated with prior covering methods.

The bolts then pass a final cooling station provided by blowers 40 toreduce or remove any heat build-up that may have resulted from exposureto the ultraviolet lights and to better prepare the bolts for deposit inbulk shipping containers 42 at the end of the conveyor immediately afterthe radiation treatment. Cooling air raises the viscosity of thedeposits which gives support to and strengthens the skins so that thedeposits remain intact when the bolts are discharged into the containers42 and the bolts do not stick together.

In general, the ultraviolet curable material mixed with the resin ofdeposit 15 and with the curing agent of deposit 17 is made up from oneor more monomers and a photoinitiator. Such ultraviolet curable materialis activated to form a skin on the deposits by a photochemical reaction.

Typical monomers that may be used include chemical compounds which areclassified as acrylic esters, methacrylic esters, vinyl esters, vinylethers, acrylic ethers, allyl esters, allyl ethers, epoxides, styreneand substituted acrylamides, acrylonitrile, and dienes. A particularlygood monomer for the purposes of this invention is trimethylopropanetriacrylate (TMPTA).

The photoinitiators can include ketones, benzophenones, aromaticketones. Michler's ketones, benzoin ethers, alkyl aryl ketones, benzilketals, oxime esters, halogenated thioxanthones, Onium salts,fluoborates, peroxides, azo free radical generators, and promoters liketertiary amine accelerators, organometallic complexes and mixtures ofthe above.

The locking resin chosen for the deposits 15 must be of a nature whencured to adhesively resist separation of two threadedly engaged members.As stated, epoxy is a particularly good resin for this purposes, asuitable example being bis-phenol A resins which are commerciallyavailable.

The curing agent selected for the deposit 17 should be one which readilyeffects a cure of the resin in deposit 15 when the two are mixed. Atertiary amine has been found to be an effective curing agent for anepoxy resin.

Ultraviolet radiation is preferred because of convenience, readyavailability, and economy, and also because it accomplishes its purposeeffectively and very quickly. However, other types of radiation may beemployed, such, for example, as electron beam radiation.

As mentioned above, TMPTA has been found to be an outstanding monomer.It will not react with the resin or with the curing agent when mixedwith them. However, when the deposits 15 and 17 are mixed together tocure the epoxy, as when two fasteners are threaded together, the TMPTAdoes correct with the epoxy, so that that portion below the surfacewhich does not cure in the ultraviolet light will compliment the endresult. This has been proven to be true under torque tests of twothreadedly engaged fasteners at temperatures as high as 400° F.

The deposits 15 and 17 of locking resin plug ultraviolet curablematerial and of hardener or curing agent plus ultraviolet curablematerial preferably have compositions by weight in the following ranges:

    ______________________________________                                        Resin Deposit 15  Hardener Deposit 17                                         ______________________________________                                        15%-74% locking resin (A)                                                                       15%-74% hardener (D)                                        20%-75% monomer (B)                                                                             20%-75% monomer (B)                                          1%-10% photoinitiator (C)                                                                       1%-10% photoinitiator (C)                                  ______________________________________                                    

    ______________________________________                                        Hardener Deposit 17                                                           Example 1     100 ml tertiary amine (D)                                                      75 ml acrylate monomer (B)                                                    3 ml aromatic hydroxy ketone (C)                               Resin Deposit 15                                                                          100 ml epoxy resin (A)                                                         35 ml acrylate monomer (B)                                                    1.4 ml aromatic hydroxy ketone (C)                               Hardener Deposit 17                                                           Example 2     100 ml tertiary amine (D)                                                      75 ml TMPTA (B)                                                               3 g   thioxanthone (C)                                         Resin Deposit 15                                                                          400 ml epoxy resin (A)                                                        140 ml TMPTA (B)                                                               9.8 g.  Michler's ketone (C)                                     ______________________________________                                    

In the foregoing examples, the capital letters in parentheses followingeach component represents the appropriate category as described in thematerial immediately proceding the examples.

The method of this invention has a number of advantages over priormethods, in particular the method involving the use of a subsequentlyapplied water base cover coat or skin. Among the advantages are:

(a) It is possible to substantially reduce the overall length of theconveyor apparatus used to practice the invention and to increase thespeed of the conveyor, thereby substantially reducing production time.

(b) The need for blowers and dryers, etc. to drive off the aqueous ororganic solvent in a cover coat is eliminated, reducing overall powerconsumption.

(c) Pin holes and imperfections in the cover coat for the deposits areno longer a problem since the generation of a skin by ultraviolet lightis uniform and total. Pin holes are simply not acceptable. They permitescape of the deposits and can cause skin problems for anyone handlingthe parts.

(d) A cover or skin cured by ultraviolet light according to the presentinvention makes the deposits water and solvent proof in contrast to someother types of self-locking deposits.

(c) Since the ultraviolet curable material is mixed with the depositsrather than subsequently applied, such material covers only the depositsthemselves and does not get into the spaces between the deposits whereit might interfere with a successful mixing of the deposits when thefasteners are engaged.

This method lends itself readily to mass production of friction lockingfasteners which may be collected at random at the end of the conveyorline immediately after being exposed to radiation. The film or skinformed on the deposits is then, dry, flexible and non-tacky so that therandomly collected fasteners do not stick together and the locking resinand hardener are covered and well protected against displacement orloss. When one of these fasteners is engaged with a mating threadedmember, the two deposits are mixed together, effecting a cure of theresin to provide a thread lock.

In the foregoing, a mass production method has been described in whichthe uncured fluid resin and fluid actuator or hardener are deposited ona threaded zone in side-by-side relation, each deposit including anultraviolet curable material which when subjected to ultraviolet lightforms a protective film over the deposits.

However, the invention is also applicable to mass production of threadedarticles in which the resin and/or hardener may be micro-encapsulated.

It has been suggested that thread locks may be formed by suitablysupporting a liquid or fluid locking material in microscopic, pressurerupturable capsules located in the thread grooves of a threaded article.

In accordance with my own prior U.S. Pat. No. 4,325,985, one or both ofthe resin and hardener are micro-encapsulated and deposited in athreaded zone, the deposit subsequently being spray coated with anultraviolet curable material which is exposed to radiation to form aprotective film. Some of the capsules rupture when the article isthreaded into a mating threaded article to effect polymerization.

In accordance with the present invention, the material to be depositedmay contain a mixture of micro-encapsulated uncured fluid resin in asuitable fluid hardener or polymerizing agent for the resin, and anultraviolet curable material. The hardener, instead of the resin, mayalso, if desired, be microencapsulated, or both may bemicro-encapsulated.

The resin, hardener, and ultraviolet curable material may be of the samematerial as heretofore described.

In accordance with the invention, this mixture of resin and hardener, atleast one of which is micro-encapsulated, and including the ultravioletcurable material, may be serially applied to the articles as they passan applicator station. This may be the station B in FIG. 3, where themixture may be applied at one side of the articles 10, or at both sides.In the latter case, the fluid mixture may flow around the thread groovesto form a 360° ring. Fluidity and viscosity are preferably such as toprevent substantially flow axially across the thread grooves.

Substantially immediately after application of the fluid mixture, themixture is exposed to a very brief radiation treatment by ultravioletlamps. This may be at station C in FIG. 3, where ultraviolet sensitivematerial at the surface of the deposits is set into an extremely thin,flexible, dry, non-tacky, protective cover film. The films cover thedeposits, so that the articles do not stick together. The time ofexposure to ultraviolet light is the same as that described in theprevious embodiment. Protected by the film is the mixture containing theresin and the hardener. Since the resin or hardener or both have beenmicro-encapsulated, the resin and hardener are separated from oneanother to prevent premature mixing and polymerization of the resin.

In U.S. Pat. No. 3,746,068 there is suggested microencapsulation of anunpolymerized resin in a fluid binder to produce a mixture suitable forapplication to the threads of a threaded article. The binder includesfluids or liquids such as toluene, all capable of being eliminated byevaporation, thus requiring a protracted drying period in the absence ofa protective film.

In accordance with the present invention, the fluid deposit is protectedby a film which is formed substantially immediately followingapplication of the deposit, so that no protracted drying period isnecessary. No binder is necessary nor is one present in the mixture.Even if both the resin and hardener are micro-encapsulated, theradiation curable material serves the purpose of holding the mixturetogether in a fluid slurry until the protective film is formed.

Prior U.S. Pat. No. 3,814,156 discloses a mixture of separatelymicro-encapsulated two part adhesives in a fluid binder, again requiringa protracted drying period. before the threaded articles can be randomlyaccumulated without sticking.

For a more complete description of the capsules, reference is again madeto my own prior U.S. Pat. No. 4,325,985 as well as the other patentsdisclosed herein.

When a fastener having a deposit as herein described, in which one orboth the resin and hardener have been microencapsulated, is engaged in amating threaded member, the microcapsules rupture so that the resin andhardener mix together, curing the resin to a solid state and producing athread lock. The protective film over the deposit breaks up and "balls"up and assists in rupturing the capsules.

I claim:
 1. The method of making a threaded friction locking articleprovided with thread locking means adapted to resist separation from amating threaded member which comprises placing at a first location onthe threaded surface of the article a first deposit .[.comprising.]..Iadd.consisting essentially of .Iaddend.a fluid mixture of an uncuredresin .[.and.]. .Iadd.having throughout .Iaddend.a radiation-curable,film-forming material so that a very thin .Iadd.integral .Iaddend.filmcoating of said radiation-curable, first-forming material develops atthe surface of said first deposit, placing at a second location spacedcircumferentially from said first location on said threaded surface asecond deposit .[.comprising.]. .Iadd.consisting essentially of.Iaddend.a fluid mixture of a curing agent for the resin .[.and.]..Iadd.having throughout .Iaddend.a radiation-curable, film-formingmaterial so that a very thin .Iadd.integral .Iaddend.coating of theradiation-curable, film-forming material develops at the surface of saidsecond deposit, and thereafter initiating a brief high intensityradiation of the radiation-curable film-forming material at the surfacesof said deposits to transform the same into thin, .Iadd.integral,.Iaddend.continuous, flexible, non-tacky outer protective films whichcover the still fluid mixtures on the threaded surface of the article,said films being rupturable to permit intermixing of said resin andcuring agent and curing of said resin.
 2. The method as defined in claim1, which comprises supporting the article with its axis vertical duringdeposition of the two deposits and radiation thereof, in which saiddeposits when deposited have a viscosity which permits flow thereof downinto the thread grooves and laterally along the thread grooves whilepreventing substantial flow longitudinally of the article.
 3. The methodas defined in claim 1, wherein said radiation-curable material in eachdeposit includes trimethylopropane triacrylate.
 4. The method as definedin claim 1, which comprises applying the deposit in the thread groovesat a temperature of about 90° F.
 5. The method as defined in claim 1, inwhich the first deposit comprises a mixture by weight of about 15%-74%of the resin, about 20%-75% of a monomer, and about 1%-10% of aphotoinitiator.
 6. The method as defined in claim 1, in which the seconddeposit comprises a mixture by weight of about 15%-74% of the curingagent, about 20%-75% of a monomer, and about 1%-10% of a photoinitiator.7. The method of mass producing articles by the method defined in claim1, which comprises continuously advancing a series of articleshorizontally through a deposit station and making the deposits in thethread grooves as the articles advance, and subjecting the deposits toultraviolet radiation at a radiation station beyond the deposit stationas the articles continue to advance.
 8. The method of mass producingarticles by the method defined in claim 7, which comprises collectingthe finished articles at random immediately after exposure to theultraviolet radiation.
 9. The method defined in claim 8, in which saidfirst deposit comprises a mixture by weight of about 15%-74% of epoxyresin, about 20%-75% of a trimethylopropane triacrylate, and about1%-10% of a photoinitiator.
 10. The method as defined in claim 8, inwhich said second deposit comprises a mixture by weight of about 15%-74%of an amine curing agent, about 20%-75% of trimethylopropanetriacrylate, and about 1%-10% of a photoinitiator.
 11. The method ofproducing a threaded article provided with thread locking means adaptedto resist separation from a mating threaded article which comprisesdepositing a fluid lock-forming material on the threaded surface of thearticle to be received in the thread grooves and fill the bottoms of thethread grooves, the fluid material .[.comprising.]. .Iadd.consistingessentially of .Iaddend.a fluid mixture including uncured resincontained in micro-capsules .[.,.]. .Iadd.and .Iaddend.a curing agentfor the resin.[., and.]. .Iadd.having throughout .Iaddend.aradiation-curable film-forming material, and thereafter subjecting theradiation-curable material at the surface of said deposit to radiationto transform the same into .[.a.]. .Iadd.an integral, .Iaddend.thin,continuous, flexible, non-tacky outer protective film which covers thestill fluid mixture in the thread grooves of the article, said film andmicro-capsules being rupturable to permit intermixing of said resin andcuring agent and curing of said resin.
 12. The method as defined inclaim 11, wherein the radiation-curable material includestrimethylopropane triacrylate.
 13. The method as defined in claim 11,wherein said radiation-curable material comprises a monomer and aphotoinitiator.
 14. The method as defined in claim 13, in which themonomer is trimethylopropane triacrylate.
 15. The method as defined inclaim 1, in which the radiation-curable material includes a monomer anda photoinitiator, the monomer is trimethylopropane triacrylate, and theradiation-curable material is subjected to ultraviolet radiation. 16.The method of producing a threaded article provided with thread lockingmeans adapted to resist separation from a mating threaded article whichcomprises depositing a fluid lock-forming material on the threadedsurface of the article to be received in the thread grooves and fill thebottoms of the thread grooves, the fluid material .[.comprising.]..Iadd.consisting essentially of .Iaddend.a fluid mixture of an uncuredresin and a fluid curing agent for said resin, one of which is containedin micro-capsules, said mixture .[.also including.]. .Iadd.havingthroughout .Iaddend.a radiation-curable film-forming material, andthereafter subjecting the radiation-curable material at the surface ofsaid deposit to radiation to transform the same into .[.a.]. .Iadd.anintegral, .Iaddend.thin, continuous, flexible, non-tacky outerprotective film which covers the still fluid mixture in the threadgrooves of the article, said film and micro-capsules being rupturable topermit intermixing of said resin and curing agent and curing of saidresin.
 17. The method as defined in claim 1 in which the radiationcurable material comprises a monomer and a photoinitiator.